I have the manual and it shows the pinout for analog mode and digital mode.
RGBI
1 - Chassis Ground
2 - Chassis Ground
3 - Red
4 - Green
5 - Blue
6 - Intensity
7 - Reserved
8 - Horizontal Sync
9 - Vertical Sync
RGB Analog
1 - Chassis Ground
2 - Chassis Ground
3 - Red
4 - Green
5 - Blue
6 - Reserved
7 - Composite Sync
8 - Reserved
9 - Reserved
It looks like the RBGI implementation is compatible with CGA (the manual shows a drawing labeled IBM PC). It looks like you can make a cable to make the Apple IIgs work with this, as well. It also looks like the Analog RGB implementation is similar to the Commodore 1084 9 pin, except those "Reserved" pins seem to have actual names on the 1084.
The switch in the front has four positions:
1 - Display analog RGB (4096 colors)
2 - Dispay green screen*
3 - Display RBGI 16 colors
4 - Video composite (NTSC) or Chroma/Luma
Note: the RCA jack for composite "Video" is also used for "Luma" when using the Chroma jack
* For green screen, if in analog (position 1), switch to position 2 for green screen of analog signal. If in RGBI (position 3), switch to position 2 for green screen of digital signal.
Here are some specs of note:
Video Bandwidth: 4.5 MHz (NTSC), 12 MHz RGBI
Resolution: 580x240
Horizontal Frequency: 15.7 KHz
Vertical Frequency: 50/60 Hz